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Poly(arylene piperidinium)s are attractive anion exchange membranes (AEMs) for alkaline membrane fuel cells and water electrolyzers because of their high chemical stability and hydroxide conductivity. Here, ether- and fluorine-free hydroxide conducting poly(quaterphenyl piperidinium) membranes with very similar ion exchange capacity (IEC), but different ratios of meta to para connectivity in the q
