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Synthesis and reactivity studies of model complexes for dinuclear active sites in metalloenzymes

Several new polydentate and potentially dinucleating ligands have been synthesized in order to model the coordination environments of a number of structurally related dinuclear active sites in metalloenzymes, including methane monooxygenase, the ribonucleotide reductase R2 protein, urease, arginase, red kidney bean purple acid phosphatase and zinc phosphotriesterase.~ Ligands 1 and 2 have proven t

Design and Implementation of a Web-Based Simulator for Automatic Control Education

This thesis presents the design and implementation of a web-based simulator, developed to support students in the introductory course in automatic control at LTH. The simulator is meant to serve as a preparatory tool for the laboratories that revolve around two interconnected water tanks, and provides an interactive environment for students to explore system dynamics and PID control prior to atten

Increased examination frequency and learning for a large group of students early in their education

Abstract—Denna artikel beskriver hur undervisningen i grundkursen i mekanik för maskinteknik förändrades för att främja djupinlärning hos studenterna och öka examinationsfrekvensen. Strategin var baserad på utökade möjligheter för aktiv inlärning och styrning av inlärning genom att införa förändringar i examinationen. Under kursens gång implementerades kontinuerlig examination med inlämningsuppgif

Metal and Semiconductor Nanocrystals for Quantum Devices

Popular Abstract in Swedish Denna avhandling beskriver tillverkning av partiklar av metaller och halvledare samt dessas användning i nya typer av elektroniska komponenter och nanostrukturer. Partiklarna tillverkas med aerosolteknik, dels med kända metoder och dels med nyutvecklade. Partiklarna är mellan 5 och 80 nanometer (miljarddels meter) i diameter, och deras bildning, struktur och sammansättnAerosol technology was used to develop new methods for fabrication of size-selected, nanometer-sized particles of metals and semiconductors. Such particles were used to realize different types of quantum devices and nanometer-sized structures. The thesis contains an introduction, five papers on particle fabrication, and five papers on particle-based quantum devices. Size-selected gallium and indi

Equilibria, Kinetics and Mechanism for Rapid Substitution Reactions trans to Triphenyl Silyl in Platinum(II) Complexes

Fast substitution of chloride for bromide and iodide trans to triphenylsilyl in trans-PtCl(SiPh3)(PMe2Ph)2 has been studied by stopped-flow spectrophotometry in acetonitrile solution. Substitution is reversible with an observable solvent path via the solvento complex trans-[Pt(SiPh3)(MeCN)(PMe2Ph)2]+, which has also been synthesized and characterized in solution. Rate constants for the forward and

Editorial: Making Space for Hope : Exploring its Ethical, Activist and Methodological Implications

This volume is a special issue with contributions that stem from the collaborations of the 2018 AESOP PhD workshop, held 5-8 July at Tjärö island, Sweden. The overarching aim of the workshop was to establish inclusive spaces for dialogue and collaboration between PhD students across countries and continents on issues that pertained to the AESOP’s 2018 congress theme “Making space for hope”. Furthe

...And Justice for All

Costa Rica and Argentina are two countries that form part of the vast region called Latin America. These two countries differ significantly in levels of corruption according to Transparency Internationals annual index of corruption globally. Why is this so and why are certain countries more corrupt than others? This overarching question has inspired this thesis. The study more specifically aims to