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We report here a method for the determination of the pKa of histidine in complex or heterogeneous systems amenable to neither solid-state nor solution NMR spectroscopy. Careful synthesis of a fluorenylmethyloxycarbonyl- and trityl-protected, C2-deuterated histidine produces a vibrational-probe-equipped amino acid that can readily be incorporated into any peptide accessible by standard solid-phase

Nature-based solutions (NbS) are gaining traction in high-level, decision-making arenas as a response to global policy challenges. Claiming to be transformative and pluralistic, NbS aim to resolve societal problems through a focus on nature, which is understood to be a benign ally. This uncritical framing of nature may have unintended and inequitable consequences that undermine the emancipatory po

Climate change is exposing high-latitude systems to warming and a shift towards more shrub-dominated plant communities, resulting in increased leaf-litter inputs at the soil surface, and more labile root-derived organic matter (OM) input in the soil profile. Labile OM can stimulate the mineralization of soil organic matter (SOM); a phenomenon termed “priming.” In N-poor subarctic soils, it is hypo

Litter decomposing Agaricales play key role in terrestrial carbon cycling, but little is known about their decomposition mechanisms. We assembled datasets of 42 gene families involved in plant-cell-wall decomposition from seven newly sequenced litter decomposers and 35 other Agaricomycotina members, mostly white-rot and brown-rot species. Using sequence similarity and phylogenetics, we split the f

Conventional agricultural practices can lead to soil erosion and a reduction in soil organic carbon (SOC) content. It has been suggested that less intensive agricultural practices, such as conservation tillage (including no-till and reduced till without soil inversion) may reduce both erosion and loss of SOC. The aim of this study was to determine whether, and why, conservation tillage is used in

The contribution of terrestrially-derived carbon to micro-crustacean zooplankton biomass (i.e. allochthony) has been previously studied in lakes and reservoirs, but little is known about allochthony in rivers. We hypothesized that restricted selective grazing in turbulent environments such as rivers would decouple zooplankton from specific microbial and algal food resources, such that their alloch

Drought events are expected to increase as a consequence of climate change, with the potential to influence both plant and soil microbial communities. Mixed planting may be an option to mitigate drought stress to plants, however, the extent to which mixed planting mitigates the indirect effect of drought (reduced plant-derived carbon input) on soil microorganisms remains unknown. Using soils from

Improved understanding of the nutritional ecology of arbuscular mycorrhizal (AM) fungi is important in understanding how tropical forests maintain high productivity on low-fertility soils. Relatively little is known about how AM fungi will respond to changes in nutrient inputs in tropical forests, which hampers our ability to assess how forest productivity will be influenced by anthropogenic chang

Wild bees are declining in intensively farmed regions worldwide, threatening pollination services to flowering crops and wild plants. To halt bee declines, it is essential that conservation actions are based on a mechanistic understanding of how bee species utilize landscapes. We aimed at teasing apart how foraging resources in the landscape through the nesting season affected nesting and reproduc

Estuarine sediments are key sites for removal of phosphorus (P) from rivers and the open sea. Vivianite, an Fe(II)-P mineral, can act as a major sink for P in Fe-rich coastal sediments. In this study, we investigate the burial of P in the Öre Estuary in the northern Baltic Sea. We find much higher rates of P burial at our five study sites (up to ĝ1/4 0.145 molĝ€†mĝ'2ĝ€†yrĝ'1) when compa

Coexistence between great tits Parus major and blue tits Cyanistes caeruleus, but also other hole-nesting taxa, constitutes a classic example of species co-occurrence resulting in potential interference and exploitation competition for food and for breeding and roosting sites. However, the spatial and temporal variations in coexistence and its consequences for competition remain poorly understood.

Bacteria and fungi are the two principal decomposer groups in soils, determining rates of biogeochemical cycling. Rewetting of dry soils induces enormous dynamics in biogeochemistry. Bacteria have been shown to exhibit large variation in growth over time upon drying-rewetting (D/RW), however, in studies to date, fungal growth has shown limited responsiveness. Here we investigated whether fungal gr

Nature-based solutions (NBS) is the latest contribution to the green concept family. NBS is defined as actions based in nature addressing societal challenges. In this study, we lean on the concept boundary object, broken down into three analytical categories: use, core ideas and granularities, to explore the cohesive and fragmenting powers of the NBS concept, and discuss its future role in green s

Arctic and subarctic soils are typically characterized by low nitrogen (N) availability, suggesting N-limitation of plants and soil microorganisms. Climate warming will stimulate the decomposition of organic matter, resulting in an increase in soil nutrient availability. However, it remains unclear how soil microorganisms in N-limited soils will respond, as the direct effect of inorganic N additio

Soil organic matter (SOM) stores the largest quantity of C in terrestrial ecosystems. Most SOM can be decomposed by microorganisms and released as CO2 into the atmosphere. The remaining fraction of SOM can be resistant against microbial decomposition over centuries to millennia. Changes in the magnitude of this stable SOM pool can have a substantial effect on the atmospheric CO2 concentration and

Study region: Rukarara River Watershed (RRW), Rwanda. Study focus: DOC leaching has important environmental consequences for both terrestrial and aquatic ecosystems. This paper measures leached dissolved organic carbon (LDOC) and the factors controlling its variation in the RRW, a mixed agriculture and forest watershed in Rwanda. The study describes the relationship of LDOC with land use/land cove

Climate may regulate dissolved organic carbon (DOC) composition across the peat-water interface, but experimental evidence is scarce. We manipulated the climate in peatland and recipient surface water mesocosms to reflect four different climate warming scenarios. In half of the mesocosms, the water level was managed to avoid drought, after which responses were recorded during two annual cycles. It

Functional overlap among species (redundancy) is considered important in shaping competitive and mutualistic interactions that determine how communities respond to environmental change. Most studies view functional redundancy as static, yet traits within species—which ultimately shape functional redundancy—can vary over seasonal or spatial gradients. We therefore have limited understanding of how